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Nanocluster formation synthetic, kinetic, and mechanistic studies. The detection of, and then methods to avoid, hydrogen mass-transfer limitations in the synthesis of polyoxoanion- and tetrabutylammonium-stabilized, near-monodisperse 40 +/- 6 angstrom Rh(0) nanoclusters Aiken JD, Finke RG Journal of the American Chemical Society, 120(37), 9545, 1998 |
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Polyoxoanion-Supported Catalyst Precursors - Synthesis and Characterization of the Iridium(I) and Rhodium(I) Precatalysts ((N-C4H9)(4)N)(5)Na-3((1,5-Cod)M-Center-Dot-P2W15Nb3O62) (M=ir, Rh) Pohl M, Lyon DK, Mizuno N, Nomiya K, Finke RG Inorganic Chemistry, 34(6), 1413, 1995 |
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An Organometal Hydroxide Route to (((C8H12)Rh)(2)(Ti(Oprn)(6))) Day VW, Eberspacher TA, Hao JL, Klemperer WG, Zhong BX Inorganic Chemistry, 34(13), 3549, 1995 |
4 |
The Nonasodium Salt of the Triniobium-Substituted Polyoxoanion P2W15Nb3O62(9-) - a Water-Soluble, Readily Crystallized Form of This Dawson-Based Soluble Metal-Oxide Organometallics-Support System Nomiya K, Kaneko M, Kasuga NC, Finke RG, Pohl M Inorganic Chemistry, 33(7), 1469, 1994 |
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A More General-Approach to Distinguishing Homogeneous from Heterogeneous Catalysis - Discovery of Polyoxoanion-Stabilized and Bu(4)N(+)-Stabilized, Isolable and Redissolvable, High-Reactivity Ir-Approximate-to-190-450 Nanocluster Catalysts Lin Y, Finke RG Inorganic Chemistry, 33(22), 4891, 1994 |
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Novel Polyoxoanion-Stabilized and Bu(4)N(+)-Stabilized, Isolable, and Redissolvable, 20-30-Angstrom Ir-Similar-to(300)-(900) Nanoclusters - The Kinetically Controlled Synthesis, Characterization, and Mechanism of Formation of Organic Solvent-Soluble, Reproducible Size, and Reproducible Catalytic Activity Metal Nanoclusters Lin Y, Finke RG Journal of the American Chemical Society, 116(18), 8335, 1994 |