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[Cp2TiCH2CHMe(SiMe3)](+), an Alkyl-Titanium Complex Which (a) Exists in Equilibrium between a beta-Agostic and a Lower Energy gamma-Agostic Isomer and (b) Undergoes Hydrogen Atom Exchange between alpha-, beta-, and gamma-Sites via a Combination of Conventional beta-Hydrogen Elimination-Reinsertion and a Nonconventional CH Bond Activation Process Which Involves Proton Tunnelling Dunlop-Briere AF, Baird MC, Budzelaar PHM Journal of the American Chemical Society, 135(46), 17514, 2013 |
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Remarkable Reactions and Intermediates in Titanocene(IV) Chemistry: Migratory Insertion Reactions of 2,2-Disubstituted-1-alkenes, Intramolecular 1,5-sigma Bond Metathesis via epsilon-Agostic Interactions, and a Rare Example of a beta-Agostic Alkyltitanocene Complex Sauriol F, Sonnenberg JF, Chadder SJ, Dunlop-Briere AF, Baird MC, Budzelaar PHM Journal of the American Chemical Society, 132(38), 13357, 2010 |
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Synthesis, characterization and Stat3 inhibitory properties of the prototypical platinum(IV) anticancer drug, [PtCl3(NO2)(NH3)(2)] (CPA-7) Littlefield SL, Baird MC Inorganic Chemistry, 47(7), 2798, 2008 |
4 |
Detection of an eta(1)-alkene intermediate of the type [Cp2Zr(Me)(eta(1)-alkene)](+): The role of such species in metallocene catalyst deactivation to allylic species Vatamanu M, Stojcevic G, Baird MC Journal of the American Chemical Society, 130(2), 454, 2008 |
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An investigation into the identities and the relative concentrations of the Zr-polymeryl species present during ethylene and propylene polymerizations by zirconocene-based Ziegler catalysts Vatamanu M, Boden BN, Baird MC Macromolecules, 38(24), 9944, 2005 |
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Ultrahigh molecular weight copolymers of isobutene and 2,3-dimethyl-1,3-butadiene formed using a novel protic carbocationic initiator, the 1 : 2 adduct of n-octadecanoic (stearic) acid and B(C6F5)(3) Cordoneanu A, Baird MC Macromolecules, 37(18), 6744, 2004 |
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Isobutene polymerization initiated by [CP*TiMe2] in the presence of a series of novel, weakly coordinating counteranions Kumar KR, Hall C, Penciu A, Drewitt MJ, McInenly PJ, Baird MC Journal of Polymer Science Part A: Polymer Chemistry, 40(19), 3302, 2002 |
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Carbocationic alkene polymerizations initiated by organotransition metal complexes: An alternative, unusual role for soluble Ziegler-Natta catalysts Baird MC Chemical Reviews, 100(4), 1471, 2000 |
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Copolymerization of 1-hexene and ethylene catalyzed by the Ziegler catalyst Cp*TiMe3/B(C6F5)(3) Murray MC, Baird MC Journal of Polymer Science Part A: Polymer Chemistry, 38(21), 3966, 2000 |
10 |
Oxidation state(s) of the active titanium species during polymerization of styrene to syndiotactic polystyrene catalyzed by Cp*TiMe3/B(C6F5)(3), Cp*TiMe3[Ph3C][B(C6F5)(4)], and Cp*TiCl2,3/MAO Williams EF, Murray MC, Baird MC Macromolecules, 33(2), 261, 2000 |