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Synthesis and X-ray structure of the (MnCl2)-Cl-II and (MnF2)-F-III complexes of N,N'-dimethyl-2,11-diaza[3,3](2,6)pyridinophane. High-field electron paramagnetic resonance and density funtional theory studies of the Mn(III) complex. Evidence for a low-lying spin triplet state Albela B, Carina R, Policar C, Poussereau S, Cano J, Guilhem J, Tchertanov L, Blondin G, Delroisse M, Girerd JJ Inorganic Chemistry, 44(20), 6959, 2005 |
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Structure and NLO properties of layered bimetallic oxalato-bridged ferromagnetic networks containing stilbazolium-shaped chromophores Benard S, Yu P, Audiere JP, Riviere E, Clement R, Guilhem J, Tchertanov L, Nakatani K Journal of the American Chemical Society, 122(39), 9444, 2000 |
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Structures of Fe(II) complexes with N,N,N '-tris(2-pyridylmethyl)ethane-1,2-diamine type ligands. Bleomycin-like DNA cleavage and enhancement by an alkylammonium substituent on the N ' atom of the ligand Mialane P, Nivorojkine A, Pratviel G, Azema L, Slany M, Godde F, Simaan A, Banse F, Kargar-Grisel T, Bouchoux G, Sainton J, Horner O, Guilhem J, Tchertanova L, Meunier B, Girerd JJ Inorganic Chemistry, 38(6), 1085, 1999 |
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A new manganese dinuclear complex with phenolate ligands and a single unsupported oxo bridge. Storage of two positive charges within less than 500 mV. Relevance to photosynthesis Horner O, Anxolabehere-Mallart E, Charlot MF, Tchertanov L, Guilhem J, Mattioli TA, Boussac A, Girerd JJ Inorganic Chemistry, 38(6), 1222, 1999 |
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Synthesis, structure, and characterization of the new [L(OH)Fe(mu-O)Fe(OH2)L](3+) complex (L = N,N '-dimethyl-N,N '-bis(2-pyridylmethyl)ethane-1,2-diamine). Detection of an equilibrium with the protonated diamond form [LFe(mu-O)(mu-OH)FeL](3+) in acetonitrile Poussereau S, Blondin G, Cesario M, Guilhem J, Chottard G, Gonnet F, Girerd JJ Inorganic Chemistry, 37(13), 3127, 1998 |
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Structure and Electrochemical Studies of ((Trispicmeen)Clfeiiiofeiiicl(Trispicmeen))(2+) - Spectroscopic Characterization of the Mixed-Valence Feiiiofeii Form - Relevance to the Active-Site of Dinuclear Iron-Oxo Proteins Nivorozhkin AL, Anxolabeheremallart E, Mialane P, Davydov R, Guilhem J, Cesario M, Audiere JP, Girerd JJ, Styring S, Schussler L, Seris JL Inorganic Chemistry, 36(5), 846, 1997 |
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Selective Metal-Assisted Oxidative Cleavage of a C-N Bond - Synthesis and Characterization of the Mononuclear Iron(III) (Fe(Bpg)Cl-2) Complex and Its 2 (Fe(BPA)Cl-3) and (Fe(Bpe)Cl-3) Derivatives Rodriguez MC, Lambert F, Morgensternbadarau I, Cesario M, Guilhem J, Keita B, Nadjo L Inorganic Chemistry, 36(16), 3525, 1997 |
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A New Tripodal Tetradentate Ligand and Its Iron(III) Complex, as a Model for Mononuclear Nonheme Iron Active-Sites - Reactivity Studies Toward Dioxygen and Superoxide Rodriguez MC, Morgensternbadarau I, Cesario M, Guilhem J, Keita B, Nadjo L Inorganic Chemistry, 35(26), 7804, 1996 |
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Chemical Modeling of the Oxygen-Evolving Center in Plants - Synthesis, Structure, and Electronic and Redox Properties of a New Mixed-Valence Mn-Oxo Cluster - ((Mn2O2)-O-III,IV(Bisimme(2)en)(2))(3+) (Bisimme(2)En=n,N’-Dimethyl-N,N’-bis(Imidazol-4-Ylmethyl)Ethane-1,2-Diamine) - EPR Detection of an Imidazole Radical-Induced by UV Irradiation at Low-Temperature Frapart YM, Boussac A, Albach R, Anxolabeheremallart E, Delroisse M, Verlhac JB, Blondin G, Girerd JJ, Guilhem J, Cesario M, Rutherford AW, Lexa D Journal of the American Chemical Society, 118(11), 2669, 1996 |
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A 7-Coordinate Manganese(II) Complex Formed with a Single Tripodal Heptadentate Ligand as a New Superoxide Scavenger Deroche A, Morgensternbadarau I, Cesario M, Guilhem J, Keita B, Nadjo L, Houeelevin C Journal of the American Chemical Society, 118(19), 4567, 1996 |