| 1 |
Kinetics and Mechanism of the Arase-Hoshi R2BH-Catalyzed Alkyne Hydroboration: Alkenylboronate Generation via B-H/C-B Metathesis
Nieto-Sepulveda E, Bage AD, Evans LA, Hunt TA, Leach AG, Thomas SP, Lloyd-Jones GC
Journal of the American Chemical Society, 141(46), 18600, 2019 |
| 2 |
Anion-Initiated Trifluoromethylation by TMSCF3: Deconvolution of the Siliconate-Carbanion Dichotomy by Stopped-Flow NMR/IR
Johnston CP, West TH, Dooley RE, Reid M, Jones AB, King EJ, Leach AG, Lloyd-Jones GC
Journal of the American Chemical Society, 140(35), 11112, 2018 |
| 3 |
Base-Catalyzed Aryl-B(OH)(2) Protodeboronation Revisited: From Concerted Proton Transfer to Liberation of a Transient Aryl Anion
Cox PA, Reid M, Leach AG, Campbell AD, King EJ, Lloyd-Jones GC
Journal of the American Chemical Society, 139(37), 13156, 2017 |
| 4 |
Protodeboronation of Heteroaromatic, Vinyl, and Cyclopropyl Boronic Acids: pH-Rate Profiles, Autocatalysis, and Disproportionation
Cox PA, Leach AG, Campbell AD, Lloyd-Jones GC
Journal of the American Chemical Society, 138(29), 9145, 2016 |
| 5 |
Anti body-catalyzed oxy-cope rearrangement: Mechanism and origins of catalysis and stereoselectivity from DFT quantum mechanics and flexible docking
Black KA, Leach AG, Kalani MYS, Houk KN
Journal of the American Chemical Society, 126(31), 9695, 2004 |
| 6 |
A standard set of pericyclic reactions of hydrocarbons for the benchmarking of computational methods: The performance of ab initio, density functional, CASSCF, CASPT2, and CBS-QB3 methods for the prediction of activation barriers, reaction energetics, and transition state geometries
Guner V, Khuong KS, Leach AG, Lee PS, Bartberger MD, Houk KN
Journal of Physical Chemistry A, 107(51), 11445, 2003 |
| 7 |
Mechanism of ene reactions of singlet oxygen. A two-step no-intermediate mechanism
Singleton DA, Hang C, Szymanski MJ, Meyer MP, Leach AG, Kuwata KT, Chen JS, Greer A, Foote CS, Houk KN
Journal of the American Chemical Society, 125(5), 1319, 2003 |
| 8 |
Theoretical elucidation of kinetic and thermodynamic control of radical addition regioselectivity
Leach AG, Wang RX, Wohlhieter GE, Khan SI, Jung ME, Houk KN
Journal of the American Chemical Society, 125(14), 4271, 2003 |
| 9 |
A cornucopia of cycloadducts: Theoretical predictions of the mechanisms and products of the reactions of cyclopentadiene with cycloheptatriene
Leach AG, Goldstein E, Houk KN
Journal of the American Chemical Society, 125(27), 8330, 2003 |
| 10 |
The ene reactions of nitroso compounds involve polarized diradical intermediates
Leach AG, Houk KN
Journal of the American Chemical Society, 124(50), 14820, 2002 |
