1 |
NMR Study of Ligand Exchange and Electron Self-Exchange between Oxo-Centered Trinuclear Clusters [Fe-3(mu(3)-O)(mu-O2CR)(6)(4-R' py)(3)](+/0) Novitchi G, Helm L, Anson C, Powell AK, Merbach AE Inorganic Chemistry, 50(20), 10402, 2011 |
2 |
Isomerization Mechanisms of Stereo labile tris- and bis-Bidentate Octahedral Cobalt(II) Complexes: X-ray Structure and Variable Temperature and Pressure NMR Kinetic Investigations Riblet F, Novitchi G, Scopelliti R, Helm L, Gulea A, Merbach AE Inorganic Chemistry, 49(9), 4194, 2010 |
3 |
Mechanism of Pyridine-Ligand Exchanges at the Different Labile Sites of 3d Heterometallic and Mixed Valence mu(3)-oxo Trinuclear Clusters Novitchi G, Riblet F, Scopelliti R, Helm L, Gulea A, Merbach AE Inorganic Chemistry, 47(22), 10587, 2008 |
4 |
Design of Gd(III)-based magnetic resonance imaging contrast agents: Static and transient zero-field splitting contributions to the electronic relaxation and their impact on relaxivity Benmelouka M, Borel A, Moriggi L, Helm L, Merbach AE Journal of Physical Chemistry B, 111(4), 832, 2007 |
5 |
Water-exchange study revealed unexpected substitution behavior of [(CO)(2)( NO)Re(H2O)(3)](2+) in aqueous media Lehaire ML, Grundler PV, Steinhauser S, Marti N, Helm L, Hegetschweiler K, Schibli R, Merbach AE Inorganic Chemistry, 45(10), 4199, 2006 |
6 |
Relevance of the ligand exchange rate and mechanism of fac-[(CO)(3)M(H2O)(3)](+) (M = Mn, Tc, Re) complexes for new radiopharmaceuticals Grundler PV, Helm L, Alberto R, Merbach AE Inorganic Chemistry, 45(25), 10378, 2006 |
7 |
A high-frequency EPR study of frozen solutions of Gd-III complexes: Straightforward determination of the zero-field splitting parameters and simulation of the NMRD profiles Benmelouka M, Van Tol J, Borel A, Port M, Helm L, Brunel LC, Merbach AE Journal of the American Chemical Society, 128(24), 7807, 2006 |
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Inorganic and bioinorganic solvent exchange mechanisms Helm L, Merbach AE Chemical Reviews, 105(6), 1923, 2005 |
9 |
Separation and characterization of the two diastereomers for [Gd(DTPA-bz-NH2)(H2O)](2-), a common synthon in macromolecular MRI contrast agents: Their water exchange and isomerization kinetics Burai U, Toth E, Sour A, Merbach AE Inorganic Chemistry, 44(10), 3561, 2005 |
10 |
Dinuclear, bishydrated Gd-III polyaminocarboxylates with a rigid xylene core display remarkable proton relaxivities Costa J, Toth E, Helm L, Merbach AE Inorganic Chemistry, 44(13), 4747, 2005 |