| 1 |
Heme-Fe-III Superoxide, Peroxide and Hydroperoxide Thermodynamic Relationships: Fe-III-O-2(center dot-) Complex H-Atom Abstraction Reactivity
Kim H, Rogler PJ, Sharma SK, Schaefer AW, Solomon EI, Karlin KD
Journal of the American Chemical Society, 142(6), 3104, 2020 |
| 2 |
Heme-Cu Binucleating Ligand Supports Heme/O-2 and Fe-II-Cu-I/O-2 Reactivity Providing High- and Low-Spin Fe-III-Peroxo-Cu-II Complexes
Kim H, Sharma SK, Schaefer AW, Solomon EI, Karlin KD
Inorganic Chemistry, 58(22), 15423, 2019 |
| 3 |
Spin Interconversion of Heme-Peroxo-Copper Complexes Facilitated by Intramolecular Hydrogen-Bonding Interactions
Schaefer AW, Ehudin MA, Quist DA, Tang JA, Karlin KD, Solomon EI
Journal of the American Chemical Society, 141(12), 4936, 2019 |
| 4 |
Geometric and Electronic Structure Contributions to O-O Cleavage and the Resultant Intermediate Generated in Heme-Copper Oxidases
Schaefer AW, Roveda AC, Jose A, Solomon EI
Journal of the American Chemical Society, 141(25), 10068, 2019 |
| 5 |
Ligand Identity-Induced Generation of Enhanced Oxidative Hydrogen Atom Transfer Reactivity for a Cu-2(II)(O-2(center dot-)) Complex Driven by Formation of a Cu-2(II)(-OOH) Compound with a Strong O-H Bond
Quist DA, Ehudin MA, Schaefer AW, Schneider GL, Solomon EI, Karlin KD
Journal of the American Chemical Society, 141(32), 12682, 2019 |
| 6 |
Critical Aspects of Heme-Peroxo-Cu Complex Structure and Nature of Proton Source Dictate Metal-O-peroxo Breakage versus Reductive O-O Cleavage Chemistry
Adam SM, Garcia-Bosch I, Schaefer AW, Sharma SK, Siegler MA, Solomon EI, Karlin KD
Journal of the American Chemical Society, 139(1), 472, 2017 |
| 7 |
Phenol-Induced O-O Bond Cleavage in a Low-Spin Heme-Peroxo-Copper Complex: Implications for O-2 Reduction in Heme-Copper Oxidases
Schaefer AW, Kieber-Emmons MT, Adam SM, Karlin KD, Solomon EI
Journal of the American Chemical Society, 139(23), 7958, 2017 |
| 8 |
A Six-Coordinate Peroxynitrite Low-Spin Iron(III) Porphyrinate Complex-The Product of the Reaction of Nitrogen Monoxide (center dot NO(g)) with a Ferric-Superoxide Species
Sharma SK, Schaefer AW, Lim H, Matsumura H, Moenne-Loccoz P, Hedman B, Hodgson KO, Solomon EI, Karlin KD
Journal of the American Chemical Society, 139(48), 17421, 2017 |
| 9 |
A "Naked" Fe-III-(O-2(2-))-Cu-II Species Allows for Structural and Spectroscopic Tuning of Low-Spin Heme-Peroxo-Cu Complexes
Garcia-Bosch I, Adam SM, Schaefer AW, Sharma SK, Peterson RL, Solomon EI, Karlin KD
Journal of the American Chemical Society, 137(3), 1032, 2015 |
