Migration behaviour of important aromatic amines on silica gel layers has been investigated using mobile phases containing a nonionic surfactant (Triton X-100) over a wider concentration range (0.001-0.1M). Effect of factors such as pH of mobile phase and the presence of electrolyte (NaCl, NaBr), non-electrolyte (urea) and alcohol (MeOH, EtOH, PrOH, BuOH) additives on the mobility of amines was also examined. The results obtained with surfactant containing mobile phases were compared with those obtained in the absence of surfactant. The main chromatographic characteristics and separation conditions for mixtures of amines on silica plates with Triton X-100 containing mobile phases were determined. As a first attempt, aqueous solutions of mixed surfactants (Triton X-100 plus sodium dodecyl sulphate, SDS) have been utilized for superior thin layer chromatographic separations of aromatic amines.