Indian Journal of Chemical Technology, Vol.10, No.5, 483-488, 2003
Pair interaction potential energy function for some practically important refrigerants from the viscosity in the limit of zero density
An iterative inversion procedure is used to obtain the effective isotropic part of the pair-interaction potential for some pure refrigerants from the proposed correlation function for the zero density collision integrals of viscosity. The Lennard-Jones (LF12-6) potential energy function is used as the initial model potential required by the method. Over a range of reduced temperature extending from 1 to 100, this measured potential can be used in the calculation of the orientation-averaged viscosity collision integrals and the dimensionless ratios which are essential to calculate other transport properties.