This study provides coal quality, petrological, palynological and geochemical (Rock Eval) data on Permian coal seams and associated shales and mudstones of the Karoo Supergroup of the Songwe-Kiwira Coalfield, Tanzania. The coal seams, which have a cumulative thickness of 6.80 m, occur in the shale-coal-sandstone facies of the Mchuchuma Formation of Artinskian to Kungurian(?) age. Coal quality data (calorific values, volatile matter contents) and vitrinite reflectances indicate high volatile C bituminous to high volatile A bituminous coals, having relatively high ash yields (22-49 wt.%) and highly variable sulphur contents (0.17-9.2 wt.%). They could be used to fuel small-scale power generation units thereby providing electricity to nearby towns and villages. Also, the coals could be used as a substitute for wood, which is becoming increasingly scarce. In rural Tanzania, charcoal is still the main energy source for cooking, and wood is used extensively in brick kilns and for making roofing tiles. Petrological analysis indicated that the coals are dominated by dull to banded dull lithotypes, with seams at the base of the Mchuchuma Fort-nation enriched in inertinite macerals (up to 83 vol.%), whereas up-section vitrinite contents increase. Palynological analyses indicated that the assemblage in the lower Mchuchuma Formation (Scheuringipollenites assemblage) is dominated by trilete spores, whereas in the remainder of the section, non-taeniate disaccates dominate (Scheuringipollenites-Protohaploxypinus assemblage). Facies critical macerals suggest for most seams a marsh/wet forest swamp depositional setting, which is consistent with the palynological data. Rock Eval analyses indicate type II/III kerogen, with Tmax (degreesC) values ranging from 426 to 440, corresponding to the early stage of hydrocarbon generation. Thermal Alteration Indices (2 to 2+) and vitrinite reflectance levels (0.60-0.83 Ro (%) support the Rock Eval maturity assessment, and despite the predominance of terrestrial-derived organic matter, there is evidence of oil generation and expulsion in the form of cavity and fracture filling exsudatinite. (C) 2003 Elsevier B.V. All rights reserved.