Journal of Canadian Petroleum Technology, Vol.47, No.1, 22-25, 2008
Understanding the generation of dissolved silica in thermal projects: Theoretical progress
The production of silica in thermal petroleum recovery projects is a well-known phenomenon, and considerable efforts for its control are a common feature of facilities engineering in such projects. Recent work related to the generation of silica in SAGD projects has shown that the largest effect on silica production in SAGD is the steam zone pressure. Silica levels in produced water tend to increase with temperature. However, a significant suppressive effect of silica dissolution from quartz sands is provided by the presence of carbon dioxide dissolved in steam condensate. Lesser effects of silica concentration are due to ionic strength of the condensate. The carbon dioxide concentration in the steam condensate is amenable to theoretical prediction, available from recent progress in gas dissolution thermodynamics, and this allows the estimation of one of the major factors responsible for the suppression of produced water silica concentration. Other effects may be due to pH and fluid alkalinity, which are not independent of CO2 concentration. This paper is intended to provide an overview of the progress in obtaining a predictive capability, and to highlight the issues related to appropriate sampling and analytical methods that hinder simple correlations to date.