Journal of Applied Electrochemistry, Vol.25, No.6, 528-532, 1995
Methanol Electrooxidation on Carbon-Supported Pt-WO3-X Electrodes in Sulfuric-Acid Electrolyte
Electrooxidation of methanol has been studied in sulphuric acid electrolyte at 60 degrees C on carbon-supported Pt-WO3-x, electrodes employing varying amounts of WO3-x,. It is found that the electrodes containing (3:1) Pt-WO3-x, composite catalyst exhibit a higher catalytic activity towards methanol electrooxidation than platinized carbon electrodes without WO3-x. In the light of the XPS and XRD data on the carbon-supported (3:1) Pt-WOx sample, it is speculated that the WOx is present in the form of an oxyhydroxide, which can promote surface oxy-species on platinum by proton transfer.
Keywords:FUEL-CELLS;OXIDATION