화학공학소재연구정보센터
Journal of Applied Electrochemistry, Vol.25, No.6, 565-573, 1995
Modeling of Time-Dependent Performance Criteria in a 3-Dimensional Cell System During Batch Recirculation Copper Recovery
A three-dimensional electrode cell with cross-flow of current and electrolyte is modelled for galvanostatic and pseudopotentiostatic operation. The model is based on the electrodeposition of copper from acidified copper sulphate solution onto copper particles, with an initial concentration ensuring a diffusion-controlled process and operating in a batch recycle mode. Plug flow through the cell and perfect mixing of the electrolyte in the reservoir are assumed. Based on the model, the behaviour of reacting ion concentration, current efficiency, cell voltage, specific energy consumption and process time on selected independent variables is analysed for both galvanostatic and pseudopotentiostatic modes of operation. From the results presented it is possible to identify the optimal values of parameters for copper electrowinning.