The present paper reports the experimental data For density rho, Viscosity eta, and speed of sound it in (phenylacetonitrile + 1,2-dichloroethane), (phenylacetonitrile + 1,1,2-trichloroethane), (phenylacetonitrile + 1,1,2,2-tetrachloroethane), (phenylacetonitrile + trichloroethene), and (phenylacetonitrile + tetrachloroethene) over the entire range of composition at T = (303.15 to 313.15) K. These values have been Used to calculate the excess molar volumes V(E) and deviation in isentropic compressibility Delta kappa(s). The excess molar volumes and deviation in isentropic compressibility are fitted to it Redlich-Kister-type equation to derive binary coefficients and standard deviation and to elicit the specific interactions like complex formation as well as the saturation of chlorine atoms with T electrons.