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Journal of Chemical and Engineering Data, Vol.55, No.6, 2073-2076, 2010
Vapor-Liquid Equilibria of Binary Mixtures Formed by Hexan-1-ol with Chloroethanes and Chloroethenes at 95.6 kPa
Bubble-point temperatures (at 95.6 kPa) over the entire composition range are measured for the binary mixtures formed by hexan-1-ol with 1,2-dichloroethane, 1,1,2,2-tetrachloroethane, trichloroethene, and tetrachloroehene, employing a Swietoslawski type ebulliometer. Both Wilson and nonrandom two-liquid (NRTL) models are found to represent the measured liquid-phase composition versus bubble-point temperature data well. The computed values of the vapor-phase mole fractions, liquid-phase activity coefficients, and excess Gibbs energies are tabulated and briefly discussed.