화학공학소재연구정보센터
Journal of Applied Polymer Science, Vol.53, No.7, 923-932, 1994
Conducting Rubber-Like Copolymer Carbon-Fiber Composites
Electrically conductive rubberlike copolymer-carbon fiber composites have been prepared by either a solution method or a concentrated emulsion method. In the former procedure, carbon fibers were introduced with stirring in a copolymer-toluene solution, and the polymer-fiber composites were precipitated by extracting the solvent with methanol. In the latter procedure, a pastelike concentrated emulsion of copolymer-toluene solution in an aqueous solution of sodium dodecylsulfate (SDS) was first formed, and the carbon fibers were mechanically blended with the concentrated emulsion. The polymer-carbon fiber composites were precipitated by extracting the toluene and water with methanol. Four kinds of rubberlike copolymers have been used : styrene/ethylene-butylene/styrene triblock copolymer (SES), styrene/butadiene/styrene triblock copolymer (SBS), ethylene/propene/ethylene triblock copolymer (EPE), and ethylene/vinylacetate copolymer (EVA). Short (L = 0.1 mm) - and medium (L = 5 mm) -length carbon fibers were employed. The composites were hot-pressed in a Laboratory Press to form a sheet. The effects of the two methodologies on the electrical conductivity and mechanical properties of the sheets were investigated by changing the type of polymer, the size of the carbon fibers, the volume fraction of the carbon fibers in the composites, and the hot-pressing temperature. Composites with electrical conductivities in the range of 5-14 S/cm, tensile strengths in the range of 10-17 MPa, and elongations at break point larger than 200% were obtained. The conductivities of the composites prepared with the short fibers were by two orders of magnitude smaller than those prepared with medium-size fibers.