A novel template method for the preparation of boron nitride nanotubes (BNNTs) using SIC nanowire as template and ammonia borane as precursor is reported. We find out that the SiC nanowires could be effectively etched out by the vapors decomposed from ammonia borane, leading to the formation of BNNTs. The as-prepared products are well characterized by means of complementary analytical techniques. A possible formation mechanism is disclosed. The method developed here paves the way for large scale production of BNNTs. (c) 2011 Elsevier Ltd. All rights reserved.