Methacrylate end-capped diethylene glycol propyl methyl ether, 5-hexyl-1,2-diol, and 8-propyloxy-1,2-propane diol side-chain siloxanes were evaluated for potential use as hydrogels for contact lens application. The preparation of the methacrylate end-capped ether, hexane diol, and propane diol side-chain siloxanes was accomplished in two relatively simple synthetic steps : The first step consisted of the acid-catalyzed co-ring opening polymerization of octamethylcyclotetrasiloxane, tetramethylcyclotetrasiloxane, and 1-3-bis-methacryloylbutyltetramethyldisiloxane ,followed by a platinum-catalyzed hydrosilation with (in separate experiments) diethylene glycol allyl methyl ether, trimethylsilyl protected 3-allyloxy-1,2-propane diol, and trimethylsilyl protected 5-hexene-1,8-diol. The trimethylsilyl protecting group was removed using a 10% 0.1N HCl solution in X-propanol. Radical polymerization of the methacrylate end-capped ether, hexane, and propane diol side-chain siloxanes with hydrophilic monomers, such as dimethylacrylamide, and a strengthening agent, isobornylmethacrylate, resulted in transparent hydrogels possessing a wide range of water contents, high oxygen permeability, and a low modulus of elasticity and, for the propane diol sidechain siloxanes, excellent hydrolytic stability. The ether side-chain siloxane-based hydrogels exhibited poor hydrolytic stability.