화학공학소재연구정보센터
Journal of Applied Polymer Science, Vol.56, No.7, 803-815, 1995
Thermal-Degradation of Aliphatic-Aromatic Polyamides - Kinetics of N,N’-Dihexylisophthalamide Neat and in Presence of Copper Iodide
An experimental study to determine the effect of copper (I) iodide (CuI) on the rate and product distribution of degradation of a model of an aliphatic-aromatic polyamide was carried out. N,N-Dihexylisophthalamide (DHI) was reacted in both an inert argon atmosphere and a pure oxygen environment at 350 degrees C with CuI added in amounts ranging from 0 to 20% by weight. The rate of disappearance of DHI was enhanced by an order of magnitude when 0.5% by weight of CuI was added and was an increasing function of increasing CuI loading. Reaction in pure O-2 increased the rate of DHI degradation by two orders of magnitude over that for neat DHI pyrolysis. The rate of disappearance of DHI in O-2 was relatively unchanged when 5% CuI by weight was added. The transformations of DHI and its products are organized in terms of a set of reaction rules. This "reaction operator" formalism allowed computer generation of the reaction network and facilitated estimation of kinetic parameters.