The direct non-oxidative conversion of methane to higher hydrocarbons in non-thermal plasma, namely dielectric barrier discharge and corona discharge, has been investigated experimentally at atmospheric pressure. In dielectric barrier discharge, the methane is mainly converted to ethane and propane with small amounts of unsaturated and higher hydrocarbons. While in corona discharge, methane was activated mainly to acetylene with small amount of other higher hydrocarbons. Decreasing the gas flow or increasing power input will improve the methane conversion and product yields. It is found that the methane conversion and main product yield against the input specific energy were special functions in both dielectric barrier discharge and corona discharge, independent of the reactor size, and whether fixing flow rate or power input and changing the power input or flow rate. The corona discharge is a promising alternative method for methane conversion to produce acetylene and hydrogen at low temperature.