The excitation capability of an argon microwave plasma flame expanded at atmospheric pressure has been studied. For this purpose, argon with different proportions of nitrogen was introduced at the end of the expanded flame, where the population densities of the atomic argon levels were still high enough. Optical emission spectra allowed the identification of different excited species in the plasma. When argon containing nitrogen was added at the end of the plasma flame, all argon lines emitted in this region were highly quenched, emission due to species containing nitrogen (NH, CN) was enhanced and a noticeable increase in the emission of N(2) (C(3)Pi(u) - B(3)Pi(g)) was observed. On the contrary, the weak emission of N(2)(+) (B(2)Sigma(+)(u) - X(2)Sigma(+)(g)) was scarcely affected. According to these results it is possible to conclude that metastable argon atoms from the expanded flame are the main energy carriers when generating N(2) reactive species in this plasma zone.