The traditional use of the laser diffraction technique provides line-of-sight liquid spray drop-size distribution. However, deconvolution of the measurements can be performed for axisymmetric spray in order to determine local spray characteristics. In a previous publication, a new deconvolution technique making use of the maximum entropy principle was established and applied to determine the local drop-size distributions. The entire approach was experimentally validated. In this work. the technique is employed to determine local extinction coefficient values. As in the previous investigation, the measurement procedure consists of scanning a laser beam through the spray cross-section from the center to the edge of the spray. By use of the transmittance theory, the local extinction coefficients allow the local volume concentrations to be calculated. This theory introduces the mean scattering coefficient. The results show that this coefficient must be determined as a function of the Sauter mean diameter in order to avoid overestimation of the Volume concentration. Although no proper validation is presented, the coherence of the overall approach is discussed in detail and solutions for improving the spatial resolution are presented. Finally. the local volume concentrations are combined with the local drop-size distribution to provide local volume-weighted, drop-size distributions. These distributions provide information on the localization of the drops according to their diameter as well as on the spatial liquid distribution. This work illustrates applications and performances of laser diffraction technique that are rarely used.