Journal of Applied Polymer Science, Vol.61, No.12, 2075-2084, 1996
Effects of Gamma-Irradiation, Irradiation Environment, and Postirradiation Aging on Thermal and Tensile Properties of Ultrahigh Molecular-Weight Polyethylene Fibers
The effects of gamma irradiation in four types of irradiation environment on the thermal and tensile properties of gel-spun, ultrahigh molecular weight polyethylene fibers (Spectra(TM) 1000) have been investigated. The gamma irradiation was conducted at 2.5 Mrad and in air, nitrogen, acetylene, and vacuum to study the effects of irradiation media on the aforementioned properties. Thermal and tensile properties of virgin and irradiated fiber samples were examined using differential scanning calorimetry and an Instron tensile tester, respectively. The results indicate that both gamma irradiation and irradiation environment affected the properties of the polyethylene fibers, and substantial changes were observed for the oxygen-containing environment. The tensile-fractured surfaces of the fibers were examined by scanning electron microscopy. The properties of irradiated fibers were further evaluated at 160 days postirradiation and found to be affected, substantially. The postirradiation aging significantly decreased the tensile strength and elongation of the irradiated fibers, indicating that polyethylene fibers should not be exposed to gamma irradiation.