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Journal of Applied Polymer Science, Vol.62, No.4, 713-719, 1996
Preparation of High-Modulus Poly(Ethylene-Terephthalate) Fibers by Vibrating Hot Drawing
A novel drawing method, vibrating hot drawing, was successfully applied to poly(ethylene terephthalate) fiber, which has a normal molecular weight (IV = 0.7 dL/g) and was prepared by melt spinning. The process was divided into three steps, with differing conditions in drawing temperature, applied tension, vibrating frequency, and amplitude. The drawing temperature and vibration frequency were decided by considering the cu, dispersion of the polymer. In spite of a low draw ratio (7.7) and a low crystallinity (0.55), the birefringence and dynamic storage modulus at room temperature of the 3rd-step fiber reached 0.260 and 36 GPa, respectively. The modulus remains at a high level at elevated temperatures, for example, 29 GPa at 100 degrees C and 17 GPa at 200 degrees C. Further, it was found from temperature and intensity of the cu, dispersion peak that the movements of amorphous chains are strongly inhibited.
Keywords:MOLECULAR-WEIGHT POLY(ETHYLENE-TEREPHTHALATE);MECHANICAL-PROPERTIES;ORIENTED POLY(ETHYLENE-TEREPHTHALATE);POLYETHYLENE TEREPHTHALATE;INTRINSIC BIREFRINGENCE;ANNEALING METHOD;PET FIBERS;CRYSTALLIZATION;SUPERSTRUCTURE;DEFORMABILITY