In previous papers, the synthesis and characterization of OH-terminated glycidyl azide-r-(3,3-bis(azidomethyl)oxetane) copolymers (GA/BAMO) and poly-3-azidomethyl-3-methyl oxetane (pAMMO) by azidation of their respective polymeric substrates were described. The main objective was the preparation of amorphous azido-polymers, as substitutes of hydroxy-terminated polybutadiene (HTPB) in new formulations of energetic propellants. Here, the subsequent characterization of both the binders is presented. First of all, several isocyanates were checked in order to optimize the curing reaction, and then two small-scale formulations of a propellant, based on aluminium and ammonium perchlorate, were prepared and characterized. Finally, the mechanical properties and burning rate were compared to those of a similar propellant based on HTPB as binder.