Przemysl Chemiczny, Vol.82, No.8-9, 899-901, 2003
New directions in the modification of epoxy resins
Com. epoxy resins, Bakelite's Ruetapox 0162 and Vantico's Araldite GY 793 (containing active diluents), were modified with 5, 10, or 15 wt.% of 9-(2,3-epoxypropyl)carbazole, or 5(9-carbazolyl)methyl-1,3-oxothiolane-2-thione, or with their 3,6-dichloro- or 3,6-dibromo-derivatives to prepare homogeneous compositions that were crosslinked with isophorone diamine. Unique materials were obtained. Fluorescence spectrophotometry of the spin-coats (less than or equal to300 mum thick) made of the modified resins, gave spectra typical of isolated carbazole molecules (emission max. at 348 and 365 nm) and a few times as intensive as those of poly(9-vinylcarbazole). The 3,6-derivatives shifted the maxima of photoluminescence. Modification kept the original resin strength, hardness and thermal stability unaffected, reduced slightly water gain and flammability (O-2 index) (except for the 3,6-derivatives as modifiers), provided high adhesion to various substrates and a good thin-film formability; and made application for LED construction possible.