화학공학소재연구정보센터
Journal of Applied Polymer Science, Vol.65, No.2, 391-397, 1997
Miscibility of Conductive Blends of Poly(O-Anisidine) with Poly(2-Alkyl-2-Oxazoline)S
HCl-doped poly(o-anisidine) (PANIS-HCl) and undoped poly(o-anisidine) (PANIS-base) were blended with poly(2-methyl-2-oxazoline)(PMOx) or poly(2-ethyl-2-oxazoline) (PEOx) by solution casting from dimethyl sulfoxide. Blends containing 50 wt% or less of PANIS-HCl or PANIS-base were flexible and homogeneous. The glass transition temperature of the blend continuously shifted away from that of PMOx or PEOx with increasing PANIS-HCl or PANIS-base content, indicating miscibility. The shift in the T-g value was larger for the PMOx blend than for the corresponding PEOx blend, suggesting a stronger interpolymer interaction in the former blend. Fourier transform infrared spectroscopic studies indicated the presence of specific interactions in the blends as evidenced by the changes of C=O and NH bands. Blends containing 50 wt% of PANIS-HCl showed conductivity of about 10(-4) S/cm.