화학공학소재연구정보센터
Solar Energy Materials and Solar Cells, Vol.80, No.1, 21-31, 2003
Effect of spatial variation of incident radiation on spectral response of a large area silicon solar cell and the cell parameters determined from it
Effect of spatial variation of incident monochromatic light on spectral response of an n(+)-p-p(+) silicon solar cell and determination of diffusion length of minority carriers (L-b) in the base region and the thickness of the apparent dead layer (x(d)) in the n(+) emitter from the spectral response have been investigated. Spectral response of a few 10 cm diameter and 10 x 10 cm(2) pseudo-square silicon solar cells was measured with the help of a standard silicon solar cell of 2 x 2 cm(2) area in 400-1100 nm wavelength range. Different areas (4, 9, 16, 25 and total area 78.6 or 96 cm(2)) were exposed. The effect of the radial variation of incident radiation was determined quantitatively by defining a parameter f(1) as the ratio of the average intensity falling on the reference cell to that on the exposed area of the test cell. The value off, varied between 1 and 1.15 (1.25) as the exposed area of the cell varied from 4 cm(2) to 78.6 (96) cm(2) indicating that the spatial inhomogeneity of intensity increased with the increase in the exposed cell area. Short-circuit current densities, computed from spectral response data for AM1.5 spectrum were less compared to the directly measured values by a factor which was nearly equal to f(1). However, radial variation of intensity does not affect the determination of diffusion length of minority carriers in the base region (by the long wavelength spectral response, LWSR method using the measured spectral response data in 0.85 < lambda < 1.05 mum range) and the thickness of the dead layer (by the method of Singh et al. using the data of 0.45 < lambda < 0.65 mum range) significantly. (C) 2003 Elsevier B.V. All rights reserved.