Two types of photolectrochemical (PEC) solar cells, FTO/TiO2/dye/PAN, EC, PC, Pr4N+ I-, I-2/Pt/FTO, and FTO/TiO2/dye/PEO, EC, PC, KI/I-2/Pt/FTO have been fabricated using a PAN-based gel polymer electrolyte and a PEO-based plasticised polymer electrolyte. The PAN-based gel electrolyte, made of polyacrylonitrile (PAN), ethylene carbonate (EC), propylene carbonate (PC) and tetrapropylammoniumiodide (Pr4N+ I-) as the complexing salt exhibited a room temperature conductivity of 2.9 x 10(-1) S m(-1) for the composition, PAN (13%):EC (31%):PC (45%):Pr4N+I- (7%):I-2 (4%) by weight ratio. The PEO-based polymer electrolyte had a conductivity of 2.2 x 10(-3) S cm(-1) for the composition PEO (37.5%):EC (37.5%):PC (20.7%)KI (3.9%):I-2 (0.4%). These solar cells have been characterised using current-voltage characteristics and action spectra. The PAN-based solar cells had an overall quantum efficiency of 2.3%. However, the PEO-based solar cells had an overall quantum efficiency of only 0.6%. (C) 2004 Elsevier B.V. All rights reserved.