Solar Energy Materials and Solar Cells, Vol.92, No.6, 639-645, 2008
Silicon-based thin-film solar cells fabricated near the phase boundary by VHFPECVD technique
The light-soaked and annealing behaviors for silicon (Si)-based thin-film single-junction solar cells fabricated near the phase boundary using a very-high-frequency plasma-enhanced chemical vapor deposition (VHF PECVD) technique are investigated. The hydrogen dilution ratio is changed in order to achieve wide band gap hydrogenated amorphous Si (a-Si:H) and narrow band gap hydrogenated microcrystalline Si (mu c-Si:H) absorbers. Just below the a-Si:H-to-mu c-Si:H transition, highly hydrogen-diluted a-Si:H solar cells with a good stability against light-soaking and fast annealing behavior are obtained. In contrast, the solar cell fabricated at the onset of the mu c-Si:H growth is very unstable and its annealing behavior is slow. In the case of mu c-Si:H solar cells with the crystal volume fraction of 43-53%, they show the lowest light-induced degradation among the fabricated solar cells. However, it is very difficult to recover the degraded Fe-Si:H solar cells via thermal annealing. (c) 2008 Elsevier B.V. All rights reserved.
Keywords:VHFPECVD;silane coefficient;phase boundary;highly hydrogen-diluted a-Si : H;mu c-Si : H;stability