A simple and economic chemical spray pyrolysis method is used to prepare transparent and conducting boron-doped zinc oxide (B(n)ZnO) electrode having potential applications in dye-sensitized solar cells (DSSCs), The B(n)ZnO electrodes were critically characterized for their structural, morphological and electrical properties. The B(n)ZnO electrode with 2 at% boron doping showed average grain size of 20(+/- 1) nm. surface roughness of 9 nm, >= 95% transparency and resistivity of 4.5 x 10(-3) Omega cm(-1). Furthermore, doping concentration of boron could also be easily controlled for achieving desired properties. Using this electrode as a substrate in DSSCs, the solar-to-electrical conversion efficiency with N3 dye as a sensitizer was noted to be 1.53%. This work suggests that the B(n)ZnO electrodes could be used as promising alternative to presently used indium- or fluorine-doped tin oxide as substrates. (C) 2008 Elsevier B.V. All rights reserved.