In this paper we report a high-contrast complementary electrochromic device based on polyanilinetethered polyhedral oligomeric silsesquioxane (POSS-PANI) and tungsten oxide (WO(3)) The electrochromic properties, cyclic voltammetry behavior and coloration efficiency of the device are Studied. Due to the loosely packed structure of POSS-PANI, it possesses more accessible doping sites and hence gives rise to a significantly higher electrochromic contrast than polyaniline (PANI). Furthermore, the replacement of PANI with POSS-PANI as the complementary layer for WO(3) leads to an enhanced complementary effect, for which the underneath mechanism is also discussed. (C) 2009 Elsevier B.V. All rights reserved.