화학공학소재연구정보센터
Solar Energy Materials and Solar Cells, Vol.93, No.9, 1692-1695, 2009
Localized irradiation effects on tunnel diode transitions in multi-junction concentrator solar cells
Multi-junction concentrator solar cells incorporate tunnel diodes that undergo a transition from high-conductance tunneling to low-conductance thermal diffusion behavior, typically at threshold current densities of the order of 10(2)-10(3) mA/mm(2). We present experimental evidence of a prominent heretofore unrecognized dependence of threshold current density on the degree of localized irradiation, in different solar cell architectures. We also show that solar cells with non-uniform metallization can exhibit an additional spatial dependence to the tunnel diode threshold current density. These previously undiscovered phenomena - which should be observable in all non-uniformly irradiated photovoltaic tunnel diodes - are interpreted as being derived from the lateral spreading of excess majority carriers (analogous to Current spreading in light-emitting diodes (LEDs)). The consequences for concentrator photovoltaics are addressed. (C) 2009 Elsevier B.V. All rights reserved.