화학공학소재연구정보센터
Solar Energy Materials and Solar Cells, Vol.95, No.8, 2545-2548, 2011
The effect of surface treatment on omni-directional efficiency of the silicon solar cells with micro-spherical texture/ITO stacks
A "bottom-up" surface texturing method based on nozzle-sprayed microspheres and spin-coated dielectric film has been proposed. The fill factor was improved by the use of indium tin oxide (ITO) as an antireflection coating (ARC) due to an increased effective area for carrier collection. The pretreatment using HCl prior to ITO deposition was found to suppress the formation of interfacial oxide at the ITO/Si junction. An enhancement in the short-wavelength response (400-600 nm) and an improvement in the short-circuit current (J(sc)) were accomplished. The difference in the efficiency (Delta eta) between the cells fabricated with ITO incorporating micro-spherical textures (MSTs) and those by KOH texturing was 13.5% at a light incident angle of 60 degrees, comparatively larger than the difference in efficiency of 7.4% observed at normal incidence. These results demonstrate the superior omnidirectional antireflection property of the ITO+MST structure. (C) 2011 Elsevier B.V. All rights reserved.