화학공학소재연구정보센터
Thin Solid Films, Vol.517, No.1, 134-136, 2008
Infrared absorption, multiphonon processes and time reversal effect on Si and Ge band structure
We have examined the effect of Time Reversal Symmetry (TRS) on vibrational modes and on the electronic band structure of Si and Ge. Most of the primary non-interacting modes are not affected by TRS. Only phonons originating from high symmetry lines 5 and A of the Brillouin Zone (BZ) indicate extra degeneracy. Selection rules for some two and three phonons originating from high symmetry lines are determined. The states of electrons and holes described by electronic band structure due to spin-inclusion are assigned by spinor representations of the double space group. Inclusion of the TRS into the band structure results in extra degeneracy of electrons and holes, and therefore optical selection rules suppose to be modified. (C) 2008 Elsevier B.V. All rights reserved.