Thin Solid Films, Vol.517, No.7, 2171-2174, 2009
Study of flash evaporated CuIn1-xGaxTe2 (x=0, 0.5 and 1) thin films
CuIn1-xGaxTe2 thin films with x = 0, 0.5 and 1, have been prepared by flash evaporation technique. These semiconducting layers present a chalcopyrite structure. The optical measurements have been carried out in the wavelength range 200-3000 nm. The linear dependence of the lattice parameters as a function of Ga content obeying Vegard's law was observed. The films have high absorption coefficients (4.10(4) cm(-1)) and optical band gaps ranging from 1.06 eV for CuInTe2 to 1.21 eV for CuGaTe2. The fundamental transition energies of the CuIn1-xGaxTe2 thin films can be fitted by a parabolic equation namely E-g1(x) = 1.06 + 0237x - 0.082x(2). The second transition energies of the CuInTe2 and CuGaTe2 films were estimated to be: E-g2 = 1.21 eV and E-g2 = 1.39 eV respectively. This variation of the energy gap with x has allowed the achievement of absorber layers with large gaps. (C) 2008 Elsevier B.V. All rights reserved.