화학공학소재연구정보센터
Thin Solid Films, Vol.517, No.14, 4196-4198, 2009
Fabrication of dye-sensitized solar cells using TiO2-nanotube arrays on Ti-grid substrates
Self-aligned TiO2 nanotube arrays (20 mu m in length) were fabricated by anodic oxidation of Ti-grid with a thickness of 100 mu m in an ethylene glycol electrolyte with an addition of H2O (1.5 vol.%) and NH4F (0.2 wt.%). Voltage applied between Ti and Pt cathodes is 60 V at -22 degrees C. Dye-sensitized solar cell utilizing photoanode structure of TiO2-nanotube/Ti-grid was fabricated with no transparent conducting oxide (TCO) layer, in which Ti-grid replaces TCO. Overall photoconversion efficiency is very low (<05%) due to the large pore size (100 nm in diameter) of the nanotubes, which may cause insufficient dye molecules to be attached, thus limiting light harvesting. (C) 2009 Elsevier B.V. All rights reserved.