Journal of Applied Polymer Science, Vol.69, No.4, 791-797, 1998
The accelerated degradation of aqueous polyacrylamide at low temperature
The accelerated degradation of aqueous polyacrylamide at low temperature was studied. The selected degradation agents included several peroxides, such as potassium persulfate (K2S2O8), ammonium persulfate ((NH4)(2)S-2O8), hydrogen peroxide (H2O2), and the potassium persulfate-sodium thiosulfate (K2S2O8-Na2S2O3) redox system. The redox system showed the highest degradation rate at the first 2 hours, but its final degradation level was lower than that of potassium persulfate. The degradation temperature, concentration of potassium persulfate and polyacrylamide, and original molecular weight of polyacrylamide all affected the degradation rate and final degradation level.