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Thin Solid Films, Vol.518, S12-S17, 2010
Analysis of silicon germanium vapor phase epitaxy kinetics
An empirical study of the selective vapor phase epitaxy kinetics of silicon germanium (Si(1-x)Ge(x)) alloys is developed with no assumption on an atomistic mechanism. The growth kinetics are approached efficiently with a power rate law. Partial reaction orders are identified for GeH(4), HCl and B(2)H(6) precursors. A trend analysis of the partial reaction order highlights the fine characteristics of the Si(1-x)Ge(x) growth kinetics. The power rate law evidences clearly the competition interactions between Si, Ge and B. Furthermore, a partial derivative study of the power rate law enabled an accurate sensitivity analysis of the selective process. (C) 2009 Elsevier B.V. All rights reserved.
Keywords:Semiconducting silicon compounds;SiGe hydrides vapor phase epitaxy;Growth models;PMOS stressor