화학공학소재연구정보센터
Thin Solid Films, Vol.518, No.12, 3351-3354, 2010
Determination of charge carrier mobility of hole transporting polytriarylamine-based diodes
Hole transport properties of three different side chain poly(triarylamines) have been determined by means of the analysis of steady-state current-voltage characteristics using co-planar diode structures. The interpretation is based on space-charge limited models with field-dependent mobility. Mobilities between similar to 10(-8) and 10(-6) cm(2) V(-1) s(-1) are obtained. The highest mobility is achieved for poly(tetraphenylbenzidine) devices and the lowest for poly(triphenylamine) devices. Electron-rich methoxy substituents increase the mobility of poly(triphenylamine)s. A comparison of the mobility values with those obtained using organic field-effect transistors is also given. (C) 2009 Elsevier B.V. All rights reserved.