Journal of Applied Polymer Science, Vol.70, No.2, 383-387, 1998
An investigation on the modification of polypropylene by grafting of maleic anhydride based on the aspect of adhesion
Isotactic polypropylene was modified by a chemical grafting of maleic anhydride in a molten state. The degree of grafting, ranged from 0.078-0.368%, was determined by a titration method. Isotactic polypropylene modified by chemical grafting of maleic anhydride was used as an adhesive in bonding the cold-rolled steel sheets for the correlation of its bondability. It was found that the maximum adhesive strength 159 kg/cm(2) was obtained from a degree of grafting 0.217%. A higher degree of grafting was detrimental not only to the initial adhesive strength, but also to the durability aged in a wet environment. Electron spectroscopy for chemical analysis was used to analyze the failure loci, because the joint was separated by shearing.
Keywords:PEROXIDES