Thin Solid Films, Vol.519, No.10, 3162-3168, 2011
Correlation between surface damage and micro-defects in Si covered with insulating layer by implantation of He and H ions
Cz n-type Si (100) wafers covered with a 220 nm SiO(2) layer or a 170 nm Si(3)N(4) layer were singly implanted with 160 key He ions at a dose of 5 x 10(16)/cm(2) or successively implanted with 160 key He ions at a dose of 5 x 10(16)/cm(2) and 110 keV H ions at a dose of 1 x 10(16)/cm(2). Surface morphologies together with defect microstructures have been studied by means of several techniques, including optical microscopy, atomic force microscopy, and cross-sectional transmission electron microscopy (XTEM). Only surface blistering has been observed for He and H sequentially implanted SiO(2)/Si samples after annealing in temperature range up to 1000 degrees C. However, as for the He and H implanted Si(3)N(4)/Si samples, surface features including blistering and the localized exfoliation of both the top Si(3)N(4) layer and the implanted Si layer have been well demonstrated during subsequent annealing. XTEM observations reveal quite different defect morphologies in two kinds of materials under the same implantation and annealing conditions. The possible mechanisms of surface damage in two kinds of materials have been discussed and presented based on the XTEM results. (C) 2011 Elsevier B.V. All rights reserved.
Keywords:SiO(2)/Si and Si(3)N(4)/Si;Helium and hydrogen ion implantation;Surface blistering;Localized exfoliation;Defect microstructures;Transmission electron microscopy