화학공학소재연구정보센터
Thin Solid Films, Vol.519, No.15, 5078-5081, 2011
Effect of dopant concentration on the structural, electrical and optical properties of Mn-doped ZnO films
The Mn-doped ZnO (Zn(1-x)Mn(x)O) thin films with manganese compositions in the range of 0-8 at.% were deposited by radio-frequency (RF) magnetron sputtering on quartz glass substrates at room temperature (RT). The influence of Mn concentration on the structural, electrical and optical properties of Zn(1-x)Mn(x)O films has been investigated. X-ray diffraction (XRD) measurements reveal that all the films are single phase and have wurtzite structure with (002) c-axis orientation. The chemical states of Mn have been identified as the divalent state of Mn(2+) ions in ZnO lattice. As the content of Mn increases, the c-lattice constant and the optical band gap of the films increase while the crystalline quality deteriorates gradually. Hall-effect measurements reveal that all the films are n-type and the conductivity of the films has a severe degradation with Mn content. It is also found that the intensity of RT photoluminescence spectra (PL) is suppressed and saturates with Mn doping. (C) 2011 Elsevier B.V. All rights reserved.