화학공학소재연구정보센터
Thin Solid Films, Vol.520, No.9, 3510-3514, 2012
Titanium dioxide thin films prepared by electrolysis from aqueous solution of titanium-lactic acid complex for dye-sensitized solar cells
Titanium oxide (TiOx) thin films were prepared on transparent conducting substrate (fluorine-doped tin oxide) by cathodic electrolysis of a solution containing a titanium bis(ammonium lactato)dihydroxide and an ammoniurn nitrate at 323 K. Post-deposition treatment: calcination at 723 K or hot-water treatment at > 363 K promoted the growth of an anatase type crystalline phase in the TiO2 thin film, as evidenced by X-ray diffraction and X-ray photoelectron spectroscopy. The calcined films were used as electrodes of a dye-sensitized solar cells and the cells' energy conversion efficiency was comparable to that obtained with commercially available TiO2 nanopartide electrodes. (C) 2012 Elsevier B.V. All rights reserved.