The effect of the doping concentration of the blue dopant on the light emission of two color phosphorescent white organic light-emitting diodes (PHWOLEDs) doped with a blue dopant and a red dopant was investigated. The red emission was intensified at high blue doping concentration due to direct energy transfer from the blue dopant to the red dopant by charge trapping. The changes in the electroluminescence spectra could be well correlated with the light emission mechanism of the PHWOLEDs. (c) 2011 Elsevier B.V. All rights reserved.