Electrodeposition is a promising low-cost method to fabricate nanostructured thermoelectric thin films such as Sb2Te3. However, electrodeposition of crystalline Sb2Te3 without the need for additional processing and with good compositional control has presented a challenge. Here we report on the electrodeposition of crystalline Sb2Te3 thin films at room temperature from a tartaric-nitric acid electrolyte using a pulsed, potentiostatic process. The effects of synthesis conditions on the resulting microstructure and compositional homogeneity are investigated using x-ray diffraction, electron diffraction, electron microscopy, and energy dispersive x-ray spectroscopy. The composition of the Sb-Te films was found to be dependent on the interval between pulses, a result that is likely due to the slow kinetics associated with Sb2Te3 formation at the surface. We also observed a change in texture and microstructure with varied applied pulse duration: for short pulse durations a lamellar microstructure with a {000l} texture forms, whereas for longer pulse durations a more equiaxed and randomly oriented microstructure forms. The thermal conductivities of the pulsed electro-deposited films are surprisingly low at less than 2 W/K.m and are found to systematically decrease with reduced pulse time. (C) 2012 Elsevier B. V. All rights reserved.