Isothermal vapor-liquid equilibria for the binary systems of ethylene glycol monopropyl ether with 2,2-dimethylbutane and 2,3-dimethylbutane

Seonghoon Hyeong; Sunghyun Jang; Kab-Soo Lee; Hwayong Kim

Korean Journal of Chemical Engineering, Vol.30, No.2, 434-439, February, 2013

DOI10.1007/s11814-012-0129-6 Export Citation

Isothermal vapor-liquid equilibria for the binary systems of ethylene glycol monopropyl ether with 2,2-dimethylbutane and 2,3-dimethylbutane

Seonghoon Hyeong, Sunghyun Jang, Kab-Soo Lee¹, and Hwayong Kim^†

School of Chemical & Biological Engineering and Institute of Chemical Processes, Seoul National University, 559, Gwanak-ro, Gwanak-gu, Seoul 151-744, Korea
¹Environmental System Engineering, Kimpo College, San 14-1, Ponae-ri, Wolgot-myun, Gyounggi-do, Kimpo 415-761, Korea

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Isothermal vapor liquid equilibria for the binary system of ethylene glycol monopropyl ether with 2,2-dimehylbutane and 2,3-dimethylbutane were measured in a circulating water bath at 303.15, 318.15, and 333.15 K. The apparatus was in-house designed and manufactured. Consistency testing of the apparatus was done by comparing the measured vapor pressures to the calculated vapor pressures from the Antoine equation. The measured systems were correlated with a Peng-Robinson equation of state (PR) combined with Wong-Sandler mixing rule for the vapor phase, and NRTL, UNIQUAC, and Wilson activity coefficient models for the liquid phase. All the measured systems showed good agreement with the correlation results.

Keywords:Vapor-liquid Equilibria;Surfactant;Ethylene Glycol Monopropyl Ether;2,2-Dimethylbutane;2,3-Dimethylbutane

[References]

Davis MI, Chacon M, Thermochim. Acta., 190, 259 (1991)
Lai HH, Chen LJ, J. Chem. Eng. Data., 44, 251 (1999)
Lee HS, Lee H, J. Chem. Eng. Data, 41(6), 1358 (1996)
OH SG, KIM JG, KIM JD, Korean J. Chem. Eng., 4(1), 53 (1987)
Carmona FJ, Bhethanabotla VR, Campbell SW, Gonzalez JA, de la Fuente IG, Cobos JC, J. Chem. Thermodyn., 33(1), 47 (2001)
Carmona FJ, Gonzalez JA, Garcia de la Fuente I, Cobos JC, Bhethanabotla VR, Campbell SW, J. Chem. Eng. Data., 45, 699 (2000)
Ramsauer B, Neueder R, Kunz W, Fluid Phase Equilib., 272(1-2), 84 (2008)
Jang S, Shin MS, Lee Y, Kim H, J. Chem. Thermodyn., 41(1), 51 (2009)
Lee Y, Jang S, Shin MS, Kim H, Fluid Phase Equilib., 276(1), 53 (2009)
Jang S, Hyeong S, Shin MS, Kim H, Fluid Phase Equilib., 298(2), 270 (2010)
Hyeong S, Jang S, Lee CJ, Kim H, J. Chem. Eng. Data, 56(12), 5028 (2011)
Peng DY, Robinson DB, Ind. Eng. Chem. Fundamentals., 15, 59 (1976)
Hill Wong DS, Sandler SI, AIChE J., 38, 671 (1992)
Renon H, Prausnitz JM, AIChE J., 14, 135 (1968)
Abrams DS, Prausnitz JM, AIChE J., 21, 116 (1975)
Wilson GM, J. American Chem. Soc., 86, 127 (1964)
Guidelines for Evaluating and Expressing the Uncertainty of NIST Measurement Results, NIST Technical Note 1297, 1994 Edition.
NIST Chemistry Webbook, NIST Standard Reference Database Number 69, National Institute of Standards and Technology, http://webbook.nist.gov/chemistry.
DIPPR 801 Database, Design Institute for Physical Property Data;American Institute of Chemical Engineers.

[Referenced By]

[Related Articles]

[1] Davis MI, Chacon M, Thermochim. Acta., 190, 259 (1991)

[2] Lai HH, Chen LJ, J. Chem. Eng. Data., 44, 251 (1999)

[3] Lee HS, Lee H, J. Chem. Eng. Data, 41(6), 1358 (1996)

[4] OH SG, KIM JG, KIM JD, Korean J. Chem. Eng., 4(1), 53 (1987)

[5] Carmona FJ, Bhethanabotla VR, Campbell SW, Gonzalez JA, de la Fuente IG, Cobos JC, J. Chem. Thermodyn., 33(1), 47 (2001)

[6] Carmona FJ, Gonzalez JA, Garcia de la Fuente I, Cobos JC, Bhethanabotla VR, Campbell SW, J. Chem. Eng. Data., 45, 699 (2000)

[7] Ramsauer B, Neueder R, Kunz W, Fluid Phase Equilib., 272(1-2), 84 (2008)

[8] Jang S, Shin MS, Lee Y, Kim H, J. Chem. Thermodyn., 41(1), 51 (2009)

[9] Lee Y, Jang S, Shin MS, Kim H, Fluid Phase Equilib., 276(1), 53 (2009)

[10] Jang S, Hyeong S, Shin MS, Kim H, Fluid Phase Equilib., 298(2), 270 (2010)

[11] Hyeong S, Jang S, Lee CJ, Kim H, J. Chem. Eng. Data, 56(12), 5028 (2011)

[12] Peng DY, Robinson DB, Ind. Eng. Chem. Fundamentals., 15, 59 (1976)

[13] Hill Wong DS, Sandler SI, AIChE J., 38, 671 (1992)

[14] Renon H, Prausnitz JM, AIChE J., 14, 135 (1968)

[15] Abrams DS, Prausnitz JM, AIChE J., 21, 116 (1975)

[16] Wilson GM, J. American Chem. Soc., 86, 127 (1964)

[17] Guidelines for Evaluating and Expressing the Uncertainty of NIST Measurement Results, NIST Technical Note 1297, 1994 Edition.

[18] NIST Chemistry Webbook, NIST Standard Reference Database Number 69, National Institute of Standards and Technology, http://webbook.nist.gov/chemistry.

[19] DIPPR 801 Database, Design Institute for Physical Property Data;American Institute of Chemical Engineers.