Journal of Industrial and Engineering Chemistry, Vol.19, No.1, 73-79, January, 2013
Characterization of MoO3.V2O5/Al2O3 catalysts for selective catalytic reduction of NO by NH3
E-mail:
MoO3-V2O5/Al2O3 catalysts were characterized by B.E.T., XRD, LRS, XPS and TPR and the effect of MoO3 addition to alumina supported vanadia catalysts on the catalytic activity for the selective catalytic reduction of NO by ammonia was investigated. Upon the addition of MoO3, catalytic activity was enhanced and the particle size of V2O5 which is shown by the results of B.E.T., XRD and Raman spectroscopy decreased. This was one reason for increased catalytic activity. The results obtained by XPS and TPR showed that MoO3 addition to alumina supported vanadia catalysts increased the reducibility of vanadia and this was the another reason for synergy effect between MoO3 and V2O5 in MoO3-V2O5/Al2O3 catalysts.
- Vargas MAL, Casanova M, Trovarelli A, Busca G, Appl. Catal. B: Environ., 75(3-4), 303 (2007)
- Lietti L, Nova I, Ramis G, Dall'Acqua L, Busca G, Giamello E, Forzatti P, Bregani F, J. Catal., 187(2), 419 (1999)
- Si ZC, Weng D, Wu XD, Li J, Li G, J. Catal., 271(1), 43 (2010)
- Lietti L, Forzatti P, Bregani F, Ind. Eng. Chem. Res., 35(11), 3884 (1996)
- Kobayashi M, Miyoshi K, Appl. Catal. B: Environ., 72(3-4), 253 (2007)
- Lietti L, Nova I, Ramis G, Dall'Acqua L, Busca G, Giamello E, Forzatti P, Bregani F, J. Catal., 187(2), 419 (1999)
- Busca G, Lietti L, Ramis G, Berti F, Appl. Catal. B: Environ., 18(1-2), 1 (1998)
- Casagrande L, Lietti L, Nova I, Forzatti P, Baiker A, Appl. Catal. B: Environ., 22(1), 63 (1999)
- Lietti L, Ramis G, Berti F, Toledo G, Robba D, usca GB, Fozatti P, Catalysis Today., 187, 419 (1999)
- Marnellos GE, Efthimiadis EA, Vasalos IA, Appl. Catal. B: Environ., 48(1), 1 (2004)
- Nam I, Eldrige JW, Kittrel JR, Industrial & Engineering Chemistry Product Research and Development., 25, 192 (1986)
- Matralis HK, Ciardelli M, Ruwet M, Grange P, J. Catal., 157(2), 368 (1995)
- Mastikhin VM, Terskikh VV, Lapina OB, Filimonova SV, Seidl M, Knozinger H, J. Catal., 156(1), 1 (1995)
- Okazaki S, Kumasaka M, Yoshida J, Kosaka K, Industrial & Engineering Chemistry Product Research and Development., 20, 301 (1981)
- Went GT, Leu L, Bell AT, Journal of Catalysis., 134, 479 (1992)
- Lietti L, Forzatti P, J. Catal., 147(1), 241 (1994)
- Kim T, Burrows A, Kiely CJ, Wachs IE, J. Catal., 246(2), 370 (2007)
- Wachs IE, Journal of Catalysis., 124, 570 (1990)
- Centi G, Pinelli D, Ghoussoub F, Guelton M, Gengembre L, Journal of Catalysis., 130, 238 (1991)
- Paganini MC, Dallacqua L, Giamello E, Lietti L, Forzatti P, Busca G, J. Catal., 166(2), 195 (1997)
- Inomata M, Mori K, Miyamoto A, Murakami Y, Journal of Physical Chemistry., 87, 761 (1983)
- Clarebout G, Ruwet M, Matralis H, Grange P, Applied Catalysis., 76, L9 (1991)