CO hydrogenation reaction over Fe-Co catalyst; a micro-kinetic approach for studying the kinetics and mechanism of hydrocarbon formation

Mehdi Shiva; Hossein Atashi; Farhad Farshchi Tabrizi; Ali Akbar Mirzaei; Maryam Arsalanfar

Journal of Industrial and Engineering Chemistry, Vol.19, No.1, 172-181, January, 2013

DOI10.1016/j.jiec.2012.07.021 Export Citation

CO hydrogenation reaction over Fe-Co catalyst; a micro-kinetic approach for studying the kinetics and mechanism of hydrocarbon formation

Mehdi Shiva, Hossein Atashi^†, Farhad Farshchi Tabrizi, Ali Akbar Mirzaei¹, and Maryam Arsalanfar¹

Department of Chemical Engineering, University of Sistan and Baluchestan, P.O. Box 98164, Zahedan, Iran
¹Department of Chemistry, University of Sistan and Baluchestan, P.O. Box 98135-674, Zahedan, Iran

E-mail:

The study addresses an enhanced approach for study of kinetics and mechanism of CO hydrogenation over Fe-Co catalyst. Kinetic models for rate of methane, paraffin and olefin formation have been developed by LHHW approach and information that obtained from UBI_QEP calculations.

Keywords:Fischer Tropsch;ASF distribution;Kinetic modeling;UBI_QEP

[References]

Steynberg A, Dry M, Fischer Tropsch Technology, Elsevier (2006)
Botes FG, Kinetic and selectivity modeling of the iron-based low-temperature Fischer.Tropsch synthesis, Ph.D. Theses (2008)
Van der Laan GP, Beenackers AACM, Catal. Rev.-Sci. Eng., 41(3-4), 255 (1999)
Lox ES, Froment GF, Industrial and Engineering Chemistry Research., 32, 71 (1993)
Wang YN, Ma WP, Lu YJ, Yang J, Xu YY, Xiang HW, Li YW, Zhao YL, Zhang BJ, Fuel, 82(2), 195 (2003)
Yang J, Liu Y, Chang J, Wang YN, Bai L, Xu YY, Xiang HW, Li YW, Zhong B, Ind. Eng. Chem. Res., 42(21), 5066 (2003)
Teng BT, Chang J, Zhang CH, Cao DB, Yang J, Liu Y, Guo XH, Xiang HW, Li YW, Appl. Catal. A: Gen., 301(1), 39 (2006)
Chang J, Bai L, Teng BT, Zhang RL, Yang J, Xu YY, Xiang HW, Li YW, Chem. Eng. Sci., 62(18-20), 4983 (2007)
Visconti CG, Tronconi E, Lietti L, Zennaro R, Forzatti P, Chem. Eng. Sci., 62(18-20), 5338 (2007)
Kwack SH, Bae JW, Park MJ, Kim SM, Ha KS, Jun KW, Fuel, 90(4), 1383 (2011)
Ojeda M, Nabar R, Nilekar AU, Ishikawa A, Mavrikakis M, Iglesia E, J. Catal., 272(2), 287 (2010)
Storsater S, Chen D, Holmen A, Surface Science., 600, 2051 (2006)
Lin YC, Fan LT, Shafie S, Bertok B, Friedler F, Comput. Chem. Eng., 33(6), 1182 (2009)
Shiva M, Atashi H, Tabrizi FF, Mirzaei AA, J. Ind. Eng. Chem., 18(3), 1112 (2012)
Shustorovich H, Sellers H, Surface Science Reports., 31, 1 (1998)
Zeigarnik AV, Shustorovich E, Russian Journal of Physical Chemistry B., 1(4), 330 (2007)
Huo CF, Li YW, Wang J, Jiao H, Journal of Physical Chemistry C., 112, 14108 (2008)
Huo CF, Ren J, Li YW, Wang JG, Jiao HJ, J. Catal., 249(2), 174 (2007)
Inderwildi OR, Jenkins SJ, King DA, Journal of Physical Chemistry C., 112, 1305 (2008)
Bartholomew CH, Farrauto RJ, Fundamentals of Industrial Catalytic Processes, 2nd ed., John Wiley & Sons, Hoboken, New Jersey, (Chapter 6). (2006)
Post MFM, Van’t Hoog AC, Minderhoud JK, Sie ST, AIChE Journal., 35, 1107 (1989)
Dictor RA, Bell AT, Journal of Catalysis., 97, 121 (1986)
Teng BT, Chang J, Wan H, Lu J, Zheng S, Liu Y, Liu Y, Guo X, Chinese Journal of Catalysis., 28, 687 (2007)
Visconti CG, Tronconi E, Lietti L, Forzatti P, Rossini S, Zennaro R, Topics in Catalysis., 54, 786 (2011)
Paul UP, Microkinetic model of Fischer.Tropsch synthesis on iron catalysts, Ph.D. Theses, Brigham Young University (2008)

[Referenced By]

[1] Steynberg A, Dry M, Fischer Tropsch Technology, Elsevier (2006)

[2] Botes FG, Kinetic and selectivity modeling of the iron-based low-temperature Fischer.Tropsch synthesis, Ph.D. Theses (2008)

[3] Van der Laan GP, Beenackers AACM, Catal. Rev.-Sci. Eng., 41(3-4), 255 (1999)

[4] Lox ES, Froment GF, Industrial and Engineering Chemistry Research., 32, 71 (1993)

[5] Wang YN, Ma WP, Lu YJ, Yang J, Xu YY, Xiang HW, Li YW, Zhao YL, Zhang BJ, Fuel, 82(2), 195 (2003)

[6] Yang J, Liu Y, Chang J, Wang YN, Bai L, Xu YY, Xiang HW, Li YW, Zhong B, Ind. Eng. Chem. Res., 42(21), 5066 (2003)

[7] Teng BT, Chang J, Zhang CH, Cao DB, Yang J, Liu Y, Guo XH, Xiang HW, Li YW, Appl. Catal. A: Gen., 301(1), 39 (2006)

[8] Chang J, Bai L, Teng BT, Zhang RL, Yang J, Xu YY, Xiang HW, Li YW, Chem. Eng. Sci., 62(18-20), 4983 (2007)

[9] Visconti CG, Tronconi E, Lietti L, Zennaro R, Forzatti P, Chem. Eng. Sci., 62(18-20), 5338 (2007)

[10] Kwack SH, Bae JW, Park MJ, Kim SM, Ha KS, Jun KW, Fuel, 90(4), 1383 (2011)

[11] Ojeda M, Nabar R, Nilekar AU, Ishikawa A, Mavrikakis M, Iglesia E, J. Catal., 272(2), 287 (2010)

[12] Storsater S, Chen D, Holmen A, Surface Science., 600, 2051 (2006)

[13] Lin YC, Fan LT, Shafie S, Bertok B, Friedler F, Comput. Chem. Eng., 33(6), 1182 (2009)

[14] Shiva M, Atashi H, Tabrizi FF, Mirzaei AA, J. Ind. Eng. Chem., 18(3), 1112 (2012)

[15] Shustorovich H, Sellers H, Surface Science Reports., 31, 1 (1998)

[16] Zeigarnik AV, Shustorovich E, Russian Journal of Physical Chemistry B., 1(4), 330 (2007)

[17] Huo CF, Li YW, Wang J, Jiao H, Journal of Physical Chemistry C., 112, 14108 (2008)

[18] Huo CF, Ren J, Li YW, Wang JG, Jiao HJ, J. Catal., 249(2), 174 (2007)

[19] Inderwildi OR, Jenkins SJ, King DA, Journal of Physical Chemistry C., 112, 1305 (2008)

[20] Bartholomew CH, Farrauto RJ, Fundamentals of Industrial Catalytic Processes, 2nd ed., John Wiley & Sons, Hoboken, New Jersey, (Chapter 6). (2006)

[21] Post MFM, Van’t Hoog AC, Minderhoud JK, Sie ST, AIChE Journal., 35, 1107 (1989)

[22] Dictor RA, Bell AT, Journal of Catalysis., 97, 121 (1986)

[23] Teng BT, Chang J, Wan H, Lu J, Zheng S, Liu Y, Liu Y, Guo X, Chinese Journal of Catalysis., 28, 687 (2007)

[24] Visconti CG, Tronconi E, Lietti L, Forzatti P, Rossini S, Zennaro R, Topics in Catalysis., 54, 786 (2011)

[25] Paul UP, Microkinetic model of Fischer.Tropsch synthesis on iron catalysts, Ph.D. Theses, Brigham Young University (2008)