Six chelating hollow fiber membranes were prepared by radiation-induced grafting of glycidyl methacrylate onto a polyethylene hollow fiber membrane and its subsequent amination. The adsorption characteristics of Pb2+ and Pd2+ for the chelating hollow fiber membranes were presented when the solution of Pb2+ and Pd2+ permeates across the chelating membrane, respectively. The degree of grafting for glycidyl methacrylate increases with increasing monomer concentration, reaction temperature, and preirradiation dose. The adsorption of Pd2+ by chelating hollow fiber membranes modified with five kinds of amines was in the following order: diethylene triamine > hexamethyl diamine > ethylene diamine > dimethyl amine > trimethyl amine. The chelating hollow fiber membrane modified with iminodiacetic acid adsorbed Pb2+ ions much more than Pd2+.