화학공학소재연구정보센터
International Journal of Energy Research, Vol.36, No.15, 1388-1394, 2012
Investigation of an integrated hydrogen production system based on nuclear and renewable energy sources: a new approach for sustainable hydrogen production via copper-chlorine thermochemical cycles
Hydrogen production via thermochemical water decomposition is a potential process for direct utilization of nuclear thermal energy to increase efficiency and thereby facilitate energy savings. Thermochemical water splitting with a copperchlorine (Cu-Cl) cycle could be linked with nuclear and renewable energy sources to decompose water into its constituents, oxygen and hydrogen, through intermediate Cu and Cl compounds. In this study, we analyze a coupling of nuclear and renewable energy sources for hydrogen production by the Cu-Cl thermochemical cycle. Nuclear and renewable energy sources are reviewed to determine the most appropriate option for the Cu-Cl cycle. An environmental impact assessment is conducted and compared with conventional methods using fossil fuels and other options. The CO2 emissions for hydrogen production are negligibly small from renewables, 38 kg/kg H-2 from coal, 27 kg/kg H-2 from oil, and 18 kg/kg H-2 from natural gas. Cost assessment studies of hydrogen production are presented for this integrated system and suggest that the cost of hydrogen production will decrease to $2.8/kg. Copyright (c) 2011 John Wiley & Sons, Ltd.